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Department of Earth and Planetary Sciences

Dr Karen Hudson-Edwards Hudson-Edwards

Senior Lecturer in Environmental Geochemistry and Mineralogy

Department of Earth and Planetary Sciences
Birkbeck, University of London
Malet St
London WC1E 7HX

Tel 020 7679 7715
Fax 020 7679 2867

email: k.hudson-edwards@bbk.ac.uk


Teaching

  • Introduction to Geochemistry (1st year)
  • Skye field class (1st year)
  • Forensic Geology (2nd year)
  • Chemistry of the Earth's Surface Environment (3rd-4th year)
  • Earth's Resources and Raw Materials (3rd-4th year)
  • Hydrogeology and Pollution (3rd-4th year)
  • MRes Frontiers in Earth Sciences
  • MRes Research Techniques in Earth Sciences
  • MRes Individual Directed Reading

Professional Affiliations

I am currently a Felow and Vice-President of the Mineralogical Society of Great Britain and Ireland. In January 2010 I will step down from this role and take on the post of Publications Manager.  On behalf of the Society and the specialist Environmental Mineralogy Group (of which I was chair from 2006-9), I am co-organising the meeting Frontiers in Environmental Geoscience 2011, which will be held in Aberystwyth, Wales, in June 2011. If anyone is interested in submitting an idea for a session for this meeting, please contact me.

I am a fellow of the Royal Geographic Society and of the Geochemical Society.


Research Interests and Publications

1. Formation, stability and contaminant uptake mechanisms of biogenic sulphate minerals on Earth and Mars

2. Biogeochemical controls on arsenic cycling in the Earth's surface environment

3. Controls on metal and metalloid cycling in mining-affected environments

4. Environmental minerals: formation, stability, contaminant uptake

5. Physical and chemical weathering in river systems


1. Formation, stability and contaminant uptake mechanisms of biogenic sulphate minerals on Earth and Mars

Jarosites [KFe3(SO4)2(OH)6] are among the most fascinating and important minerals on Earth and Mars. They occur in acid sulphate soils, acid mine wastes, saline lakes and hypogene systems, where they control the movement of toxic contaminants such as arsenic, cadmium and copper. In metallurgy, they are precipitated to remove unwanted iron and improve metal concentrates. The ancients used jarosite pigments to give distinct yellow colours to their artworks, and in 2004, jarosite was identified on Mars using Mossbaer spectroscopy. Because jarosite contains water in its structure, its presence suggests that the Martian surface was once wet and may have supported life. Research on jarosite minerals is timely because they can be used both for remediation, to immobilize toxic elements, and because they can give us insights into the potential presence of life on Mars. Using experimental and computational methods, I carry out research with colleagues on the mechanisms of formation, stability and contaminant uptake potential of jarosite and other biogenic sulphate minerals.

Current projects:

Mechanisms of formation and stability of alunite-jarosite solid solution minerals (funded by the Royal Society, with Prof. K. Wright, Nanochemistry Research Institute, Curtin University, Australia) pdf format

• Mechanisms of Al, Cd, Cu and Zn uptake in jarosite surfaces: a computer simulation study (funded by the Royal Society, with Prof. K. Wright, Nanochemistry Research Institute, Curtin University, Australia)

• Capacity and mechanisms of uptake of gold and silver by jarosite and goethite (PhD student Peter Cogram, with Dr R. Siddall, UCL)

Related publications:

Forray, F.L., Smith, A.M.L., Drouet, C., Navrotsky, A., Wright, K., Hudson-Edwards, K.A. and Dubbin, W.E. 2010. Synthesis, characterization and thermochemistry of a Pb-jarosite sample. Geochimica et Cosmochimica Acta, 74, 215-224.

Murphy, P.J., Smith, A.M.L., Hudson-Edwards, K.A., Dubbin, W.E. and Wright, K. 2009. Raman and IR spectroscopic studies of alunite-supergroup compounds containing Al, Cr3+, Fe3+ and V3+ at the B site. Canadian Mineralogist, 47, 663-681.

Hudson-Edwards, K.A., Smith, A.M.L., Dubbin, W.E., Bennett, A.J., Murphy, P.J. and Wright, K. 2008. Comparison of the structures of natural and synthetic Pb-Cu-jarosite-type compounds. European Journal of Mineralogy, 20, 241-252.

Wright, K., Hudson-Edwards, K.A., Smith, A.M.L. and Dubbin, W.E. 2008. Computer simulation studies on the mechanisms of toxic element incorporation in jarosite. AusIMM 9th International Congress for Applied Mineralogy (ICAM), pp. 369-374.

Smith, A.M.L., Hudson-Edwards, K.A., Dubbin, W.E. and Wright, K. 2006. Defects and impurities in jarosite: a computer simulation study. Applied Geochemistry, 21, 1251-1258.

Smith, A.M.L., Dubbin, W.E., Wright, K. and Hudson-Edwards, K.A. 2006. Dissolution of lead- and lead-arsenic jarosites at pH 2 and 8: insights from batch experiments. Chemical Geology, 229, 344-361.

Smith, A.M.L., Hudson-Edwards, K.A., Dubbin, W.E. and Wright, K 2006. Dissolution of jarosite [KFe3(SO4)2(OH)6] at pH 2 and 8: insights from batch experiments and computational modelling. Geochimica et Cosmochimica Acta, 70, 608-621.

Wills, A.S., Smith, A.M.L., Dubbin, W.E., Hudson-Edwards, K.A. and Wright, K. 2004. Interlayer exchange in the plumbo-jarosites: kagome systems. Journal of Magnetism and Magnetic Materials, 272-276, 1300-1301.

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2. Biogeochemical Controls on Arsenic Cycling in the Earth's Surface Environment

        

Many anoxic lake, river and groundwater systems are contaminated with arsenic (As). Consumption of these waters can lead to As toxicosis in animals, and melanosis, gangrene, cancer and ultimately, death, in humans. This is best illustrated in West Bengal and Bangladesh, which, according to the World Health Organisation, is the worst mass poisoning in the world. My colleagues and I carry out research aimed at better understanding the biogeochemical controls on arsenic pollution. I am part of the London Arsenic Group, a multi-disciplinary group carrying out research on the source, mobility, and fate, of arsenic in the environment.

       In 2006 my former PhD student Jane Archer and I, supported by funding from Birkbeck, went to San Antonio de los Cobres in northern Argentina to evaluate potential As pollution of groundwater. We were invited to work on this project with a team from His Heart Missions, who had been working in the area for some time.  We determined that drinking water in San Antonio has 25 times more As than the World Health Organization suggests is safe. Our work helped His Heart Missions to raise $70,000 to provide drinking water that is below the WHO guideline for As to every citizen of San Antonio de Los Cobres. Billy Hill Productions is producing a documentary film called 'Troubled Waters' about this important project.

Current projects:

• Studies on fluoride and arsenic contamination of drinking water in and around Lahore, Pakistan. A growing threat to human health (sponsored by the British Council, with Prof. K.J. Cheema, Lahore, Prof. J. Alam, BUET, Prof. M. Maslin, UCL Geography and Dr S. Bell, UCL Environmental Engineering)

Efficiencies and mechanisms of arsenic (As) uptake from aqueous solution by vivianite (funded by NERC, with Dr. K. Taylor, MMU) pdf format

• Low-termperature arsenite-oxidizing bacterial mechanisms in Yellowknife, NWT (with Dr J. Santini, UCL and Dr H. Jamieson, Queen's University, Kingston, Canada)

Sources of arsenic, fluoride, boron (and other elements) in waters in and around San Antonio de los Cobres, Argentina (sponsored by Birkbeck Faculty of Science) pdf format

Related publications:

McArthur, J.M., Ravenscroft, P., Banerjee, D.M., Milsom, J., Hudson-Edwards, K.A., Sengupta, S., Bristow, C., Sarkar, A., Tonkin, S. and Purohit, R. 2008. How palaeosols influence groundwater flow and arsenic pollution: A model from the Bengal Basin and its worldwide implication. Water Resources Research, 44, W11411, DOI:10.1029/2007WR006552.

Archer, J., Hudson-Edwards, K.A., Preston, D.A., Howarth, R.J. and Linge, K. 2005. Aqueous exposure and uptake of arsenic by riverside communities affected by mining contamination in the Río Pilcomayo basin, Bolivia. Mineralogical Magazine, 69, 719-736.

Hudson-Edwards, K.A., Jamieson, H.E., Charnock, J.M. and Macklin, M.G. 2005. Arsenic speciation in waters and sediments of ephemeral floodplain pools, Río Guadiamar, Aznalcóllar, Spain. Chemical Geology, 219, 175-192.

Hudson-Edwards, K.A., Houghton, S.L. and Osborn, A. 2004. Extraction and analysis of arsenic in soils and sediments. Trends in Analytical Chemistry, 23, 745-752.

McArthur, J.M., Banerjee, D.M., Hudson-Edwards, K.A., Mishra, R., Purohit, R., Ravenscroft, P., Cronin, A., Howarth, R.J., Chatterjee, A., Talukder, A., Lowry, D., Houghton, S. and Chadha, D.K. 2004. Natural organic matter in sedimentary basins and its relation to arsenic in anoxic ground water: the example of West Bengal and its worldwide implications. Applied Geochemistry, 19, 1255-1293.

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3. Controls on Metal and Metalloid Cycling in Mining-Affected Environments

             

Current projects:

• Dispersal and storage of sediment-associated metals in the Leichhardt River, Mount Isa, Australia (sponsored by Royal Geographical Society, with PhD student Alana MacKay and Dr M. Taylor, Macquarie University, Australia)

Weathering of mine tailings and its effect metal and metalloid cycling (PhD student David Kossoff, with Dr B. Dubbin, Department of Mineralogy, Natural History Museum, and Dr. M. Alfredsson, UCL)pdf format

Related publications:

Ferrier, G., Hudson-Edwards, K.A. and Pope, R.J. 2009. Characterisation of the environmental impact of the Rodalquilar Mine, Spain by ground-based reflectance spectroscopy. Journal of Geochemical Exploration, 100, 11-19.

Taylor, M.P., Mackay, A.K., Kuypers, T. and Hudson-Edwards, K.A. 2009. Mining and urban impacts on semi-arid freshwater aquatic systems: the example of Mount Isa, Queensland. Journal of Environmental Monitoring11, 977-986.

Hudson-Edwards, K.A., Macklin, M.G., Brewer, P.A. and Dennis, I.A. 2008. Assessment of Metal Mining-Contaminated River Sediments in England and Wales. Environment Agency Science Report SC030136/SR4. pdf format

Taylor, M.P. and Hudson-Edwards, K.A. 2008. The dispersal and storage of sediment-associated metals in an arid river system: the Leichhardt River, Mount Isa, Queensland. Environmental Pollution, 152, 193-204.

Macklin, M.G., Brewer, P.A., Hudson-Edwards, K.A., Bird, G., Coulthard, T.J., Dennis, I.A., Lechler, P.J., Miller, J.R. and Turner, J.N. 2006. A geomorphological approach to the management of rivers affected by metal mining. Geomorphology, 79, 423-447.

Nagaraju, A., Suresh, S., Killham, K. and Hudson-Edwards, K. 2006. Hydrogeochemistry of waters of Mangampeta barite mining area, Cuddapah basin, Andhra Pradesh, India. Turkish Journal of Engineering and Environmental Sciences, 30, 1-17.

Smolders, A., Archer, J., Stassen, M., Cavera, J.C.L. and Hudson-Edwards, K. 2006. Concentraciones metálicas en cabellos de habitantes de las orillas de la cuenca baja del río Pilcomayo. Revista Boliviana de Ecologia y Conservacion Ambiental, 19, 13-22.

Hudson-Edwards, K.A. and Edwards, S.J. 2005. Mineralogical controls on storage of As, Cu, Pb and Zn at the abandoned Mathiatis massive sulphide mine, Cyprus. Mineralogical Magazine, 69, 695-706.

Taylor, M.P. and Hudson-Edwards, K.A. 2005. Dispersal and storage of sediment-associated zinc in the Leichhardt River, Mt Isa, Australia. CRC LEME Australia Regolith Symposium Volume. pdf format

Miller, J.R., Hudson-Edwards, K.A., Lechler, P.J., Preston, D.A. and Macklin, M.G. 2004. Heavy metal contamination of water, soil and produce within riverine communities of the Río Pilcomayo Basin, Bolivia. The Science of the Total Environment, 320, 189-209.

Brewer, P.A., Macklin, M.G., Turner, J.N., and Hudson-Edwards, K.A. 2003. Geomorphological and geochemical adjustments of the Rió Guadiamar following the 1998 Aznalcóllar tailings dam failure, SW Spain. In: 21st Congress of the International Commission on Large Dams (ICOLD), International Symposium on Major Challenges in Tailings Dams, pp. 46-56. Montreal, Canada, 15th June 2003.

Hudson-Edwards, K.A. 2003. Sources, mineralogy, chemistry and fate of heavy metal-bearing particles in mining-affected river systems. Mineralogical Magazine, 67, 205-217.

Hudson-Edwards, K.A., Macklin, M.G., Jamieson, H.E., Brewer, P.A., Coulthard, T.J., Howard, A.J. and Turner, J. 2003. The impact of tailings dam spills and clean-up operations on sediment and water quality in river systems: The Ríos Agrio-Guadiamar, Aznalcóllar, Spain. Applied Geochemistry, 18, 221-239.

Miller, J.R., Lechler, P.J., Hudson-Edwards, K.A. and Macklin, M.G. 2002. Lead isotopic fingerprinting of heavy metal contamination, Rio Pilcomayo basin, Bolivia. Geochemistry: Exploration, Environment, Analysis, 2, 225-233.

Turner, J.N., Brewer, P.A., Macklin, M.G., Hudson-Edwards, K.A., Coulthard, T.J., Howard, A.J. and Jamieson, H.E. 2002. Heavy metal and As transport under low and high flows in the River Guadiamar three years after the Aznalcóllar tailings dam failure: implications for river recovery and management. In J.M. García-Ruiz, J.A.A. Jones & J. Arnáez (Editors) Environmental Change and Water Sustainability. Instituto Pirenaico de Ecología, Zaragoza, Spain, pp. 235-251.

Hudson-Edwards, K.A., Macklin, M.G., Miller, J.R. and Lechler, P.J. 2001. Sources, distribution and storage of heavy metals in the Río Pilcomayo, Bolivia. Journal of Geochemical Exploration, 72, 229-250.

Hudson-Edwards, K.A. 2000. Heavy metal-bearing Mn oxides in river channel and floodplain sediments. In J.D. Cotter-Howells, L.S. Campbell, E. Valsami-Jones and M. Batchelder (eds) Environmental Mineralogy: Microbial Interactions, Anthropogenic Influences, Contaminated Land and Waste Management. Mineralogical Society Series, 9. Mineralogical Society, London, pp. 207-226.

Hudson-Edwards, K.A., Schell, C. and Macklin, M.G. 1999. Mineralogy and geochemistry of alluvium contaminated by metal mining in the Rio Tinto area, southwest Spain. Applied Geochemistry, 14, 1015-1030.

Macklin, M.G., Hudson-Edwards, K.A., Jamieson, H.E., Brewer, P., Coulthard, T.J., Howard, A.J. and Remenda, V.H. 1999. Physical stability and rehabilitation of sustainable aquatic and riparian ecosystems in the Rio Guadiamar, Spain, following the Aznalcóllar mine tailings dam failure. In F. Rubio (ed) Mine Water and Environment. International Congress, International Mine Water Association, September 13-17, 1999, Sevilla, Spain, pp. 271-278.

Hudson-Edwards K., Macklin M. and Taylor M. 1997. Historic metal mining inputs to Tees river sediment. The Science of the Total Environment, 194/195, 437-445.

Macklin M.G., Hudson-Edwards K.A. and Dawson E.J. 1997. The significance of pollution from historic metal mining in the Pennine orefields on river sediment contaminant metal fluxes to the North Sea. The Science of the Total Environment, 194/195, 391-397.

Hudson-Edwards K.A., Macklin M.G., Curtis C.D. and Vaughan D.J. 1996. Processes of formation and distribution of Pb-, Zn-, Cd-, and Cu-bearing minerals in the Tyne basin, northeast England: implications for metal-contaminated river systems. Environmental Science and Technology, 30, 72-80.

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4. Environmental Minerals: Formation, Stability, Contaminant Uptake

   

Environmental mineralogy is a rapidly expanding field that draws upon the classical techniques and aspects of mineralogy and interfaces these with novel techniques for micro- and nano-particle and surface characterization, and with the disciplines of engineering, biogeochemistry, soil science, material sciences, medicine, chemistry and biology. Environmental minerals are not like many rock-forming minerals, because they are fine-grained, poorly crystalline and often formed by living organisms. Together with many colleagues, I carry out research on natural and synthetic analogues of these 'environmental' minerals, to determine their mechanisms of formation, their stability and how they take up and sequester contaminants.

I recently co-edited (with Heather Jamieson, Queen's University, Canada; Kaye Savage, Vanderbilt University, USA and Kevin Taylor, Manchester Metropolitan University, UK) a special issue of Canadian Mineralogist entitled 'Minerals in Contaminated Environments: Characterization, Stability, Impact'. This issue was based on a session of the same name held at the Frontiers in Mineral Sciences meeting in Cambridge, UK, in June 2007, and it includes papers reporting studies on natural, synthetic and computationally modelled, contaminated minerals.

Current projects:

• The mineralogy and geochemistry of urban road-deposited sediment (RDS): implications for risk assessment (MMU EPSRC PhD student Judi Barrett, with Dr. K. Taylor, MMU)

• Mechanisms of uranium (VI) reduction by U-respiring bacteria (UCL EPSRC PhD student Linda Dekker, with Drs. J. Santini and W. Burgess, UCL)

• Influence of microbial hydroxymate siderophores on mineral dissolution (PhD student Angela Stewart, with Dr W. Dubbin, NHM)

• Origin and weathering of V-U-Cu-Ag-As nodules at Budleigh Salterton, UK (PhD student Brian Smith, with Dr K. Taylor, MMU, and Dr P. Schofield, NHM)

• Arsenic- and lead-bearing hematite in pyrite ash wastes (with P. Canepa & Dr. M. Alfredsson, University of Kent; D. Kossoff, Birkbeck, and Dr. W. Dubbin, NHM)

Related publications:

Taylor, K.G., Hudson-Edwards, K.A., Bennett, A.J. and Vishnyakov, V. 2008. Early diagenetic vivianite [Fe3(PO4)2.8H2O] in a contaminated freshwater sediments and insights into zinc uptake: a µ-EXAFS, µ-XANES and Raman study. Applied Geochemistry, 23, 1623-1633.

Clayton, R.E., Hudson-Edwards, K.A., Malinovsky, D. and Andersson, P. 2005. Fe isotope fractionation during the precipitation of ferrihydrite and transformation of ferrihydrite to goethite. Mineralogical Magazine, 69, 667-676.

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5. Physical and Chemical Weathering in River Systems

     

Current projects:

• Chemical variation in rivers due to continental weathering over a full monsoon cycle, Goa, India. (PhD student Chris Hibbert and Dr M. Widdowson, OU)

Related publications:

Hudson-Edwards, K.A. 2007. Fluvial Environments. Chapter 3 in Environmental Sedimentology, (C. Perry and K.G. Taylor, eds.) Blackwell Scientific Publications, pp. 75-108.

Smolders, A.J.P., Hudson-Edwards, K.A., Van der Velde, G. and Roelofs, J.G.M. 2004. Controls on water chemistry of the Pilcomayo river (Bolivia, South America). Applied Geochemistry, 19, 1745-1758.

Hudson-Edwards, K.A. and Taylor, K.G. 2003. The geochemistry of sediment-borne contaminants in fluvial, urban and estuarine environments. Applied Geochemistry, 18,155-157.

Howard, A.J., Macklin, M.G., Black, S. and Hudson-Edwards, K.A. 2000. Holocene river development and environmental change in Upper Wharfedale, Yorkshire Dales, England. Journal of Quaternary Science, 15, 239-252.

Macklin, M.G., Taylor, M.P., Hudson-Edwards, K.A. and Howard, A.J. 2000. Holocene environmental change in the Yorkshire Ouse basin and its influence on river dynamics and sediment fluxes to the coastal zone. In I. Shennan and J. Andrews (eds) Holocene Land-Ocean Interaction and Environmental Change around the North Sea. Geological Society, London, Special Publication 166, pp. 87-96.

Schell, C., Black, S. and Hudson-Edwards, K.A. 2000. Sediment source characteristics of the Rio Tinto, Huelva, SW Spain. In I. Foster (ed) Tracers in Geomorphology. John Wiley and Sons, Chapter 26, pp. 503-520.

Taylor, M.P., Macklin, M.G. and Hudson-Edwards, K. 2000. River sedimentation and fluvial response to Holocene environmental change: examples from the Yorkshire Ouse Basin, Northern England. The Holocene, 10, 195-206.

Hudson-Edwards, K.A., Macklin, M.G. and Taylor, M.P. 1999. Holocene sediment-borne chemical storage in the Yorkshire Ouse basin, UK. In H. Ármannsson (ed) Geochemistry of the Earth’s Surface. Balkema, Rotterdam, pp. 99-102.

Hudson-Edwards, K.A., Macklin, M.G. and Taylor, M.P. 1999. 2000 years of sediment-borne heavy metal storage in the Yorkshire Ouse basin, NE England. Hydrological Processes, 13, 1087-1102.

Hudson-Edwards, K.A., Macklin, M.G., Finlayson, R. and Passmore, D.G. 1999. Medieval lead pollution in the River Ouse at York, England. Journal of Archaeological Science, 26, 809-819.

Hudson-Edwards, K.A., Macklin, M.G., Curtis, C.D. and Vaughan, D.J. 1998. Chemical remobilisation of contaminant metals within floodplain sediments in an incising river system: implications for dating and chemostratigraphy. Earth Surface Processes and Landforms, 23, 671-684.

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Department of Earth and Planetary Sciences, Birkbeck College, University of London, Malet Street Bloomsbury London WC1E 7HX. Departmental Office tel.: 020 7679 7333